Main Group Chemistry @ IISERTVM @MainTvm
We are Synthetic Chemists Interested in the Structure and Reactivity of Main Group Compounds. maingroupchemistrylab.com Joined June 2019-
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A cautionary tale in catalysis! Alexa, Barnabé et al's paper on the implication (or otherwise) of aluminium hydrides in carbonyl hydroboration catalysis is just out as a 'hot paper' in @angew_chem doi.org/10.1002/anie.2… @OxfordChemistry @barnacleberger @GoicoecheaGroup
We thank the editorial team of @DaltonTrans.rsc.org for inviting us to feature our #OpenAccess perspective article on the inside front cover doi.org/10.1039/D5DT00… @kritipathak04 @suban_kundu @skathayat27 @ANRFIndia @tvmiiser #maingroup
We thank the editorial team of @DaltonTrans.rsc.org for inviting us to feature our #OpenAccess perspective article on the inside front cover doi.org/10.1039/D5DT00… @kritipathak04 @suban_kundu @skathayat27 @ANRFIndia @tvmiiser #maingroup https://t.co/aphdhkxOCK
Bimetallic Al–M complexes derived from low-valent aluminium sources (M = s-/p-block metal) pubs.rsc.org/en/content/art… Hopefully a useful resource for those working with bimetallic Al–M complexes
Huge congratulations to John! His latest paper on the neutral alumene obtained via CO reduction by tetra-silyl alumane and subsequent CO homologation is now out in @NatureSynthesis! nature.com/articles/s4416…
Pre-Synopsis by Ms. Annabel Benny, from Prof. Ajay Venugopal's group. @tvmiiser
🎉 Our latest @ChemCommun work, featured in the 2025 Hot Article Collection! Congrats @LijinaMp @SuvarnaSujil @sohan_sdj @maheshhrn👏 Check more out here: pubs.rsc.org/en/content/art… @tvmiiser @Chemie_iisertvm 🎊🎉 #crossaggregate #exciton #coupling
Serendipitous Isolation of an Aldehyde Stabilised Alkoxyaluminium Dication - now published in Chemical Communications We thank @ANRFIndia for generously supporting unconventional research in traditional areas of synthetic chemistry! Treating the aluminium diation with Et3SiH…
Manjur’s paper on crystallizing and characterizing a boravinylidene is now online in @J_A_C_S. Congrats to @IamMOAkram and our collaborators Kirk French and Kevin Shuford! Check it out here: pubs.acs.org/doi/10.1021/ja…
Thrilled to share a first publication of the group! We report on cadmium aluminyls that find application as Cd-nucleophiles and(!) Al(I)-Transfer reagents. Now out in @J_A_C_S ! Thanks to @chemieverband for the generous funding of our research. pubs.acs.org/doi/10.1021/ja…
🚨 New Paper Alert! 🚨 Our latest work in ChemComm reports a new class of phenanthroline–squaramide foldamers adopting robust single-helical structures 🧬. Stable even in DMSO & at 85 °C! Kudos to @RenittaBenny & thanks to Alex, @CSIR_IND @tvmiiser pubs.rsc.org/en/content/art…
Here is our latest work on organochalcogen compounds modulating the chemistry of nitrite. Congratulations, Tuhin! pubs.acs.org/doi/10.1021/ac…
Here is our latest work showing simple copper(II) salts like CuCl2 are capable of participating in PCET. Congratulations, to the team! …mistry-europe.onlinelibrary.wiley.com/doi/10.1002/ej…
There are no examples of uranium-antimony multiple bonds, even under spectroscopic scenarios. Until now. Check out our work on U-Sb bonds spanning single, double, and pseudo-triple bonding interactions. Out now in @NatureComms! nature.com/articles/s4146…
Di-n-Butylcalcium exists! Thrilled to see this work from my previous postdoc published in @ChemistryEur. It was truly a team effort and a fantastic collaboration between @RennesUniv @chimie_ISCR and COBRA (@Labex_SynOrg) …mistry-europe.onlinelibrary.wiley.com/doi/10.1002/ce…
The aluminyl anion performing as a reducing agent... Reductive Deamination of a Diaminogermylene Promoted by an Aluminyl Anion: Isolation of Ge(I), Ge(0) and Ge(‐I) Products - Angewandte Chemie International Edition (onlinelibrary.wiley.com/doi/10.1002/an…)
@liampgriffin and I have reviewed recent advances in the heterometallic bonding chemistry of the alkaline earth metals @DaltonTrans. It was fun to put this together, and we hope it's useful! pubs.rsc.org/en/content/art…
🎊Cheers to fresh milestones! @rr_lab’s first contributions in *ACS Catalysis— A Heartfelt congratulations to Bincy, Anagha & Venkadesh for their hard work and well-deserved Achievement ! 👏 is.gd/PbS2u6 @rr_lab @rr_prof @Chemie_iisertvm @tvmiiser
Pleased to share Falk’s latest work @Ghadwal_Group on a non-classical germanium diradicaloid, just published in @angew_chem highlighting a new approach (using anionic dicarbenes) to main-group diradicaloids: onlinelibrary.wiley.com/doi/10.1002/an… #maingroup #diradicals thanks to @dfg_public
Isostructural Mg and Zn compounds: analogies and differences in reactivity - now published in Dalton Transactions pubs.rsc.org/en/content/art…
Excited to share @D4vdNdrson latest work, just accepted @angew_chem on the structure and applications of #sodium #neopentyl a donor free #organosodium reagent soluble in #hydrocarbon solvents @DCBPunibern #OpenAccess onlinelibrary.wiley.com/doi/epdf/10.10…
Angewandte Chemie @angew_chem
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