Alexander Krappe @RubiaLab
M. Sc. Chemistry, Doctoral Candidate in @EiglerLab at FU Berlin. New account @rubiaLab.bsky.social rubialab.de Berlin, Deutschland Joined March 2021-
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Check out how to spin state switch with visible light! Teamwork of @DumeleLab, Thomas Lohmiller, @sabine_richert, Philipp Thielert, and @TheGatherLab. onlinelibrary.wiley.com/doi/full/10.10…
Our latest work combining #NHCs and #photochemistry is now out in Beilstein JOC! In this paper, we investigate the reduction of acylazolium salts using DIPEA or Et3SiH. Congrats to first author Michael and the whole team! @fubcp @ChemistryNCL @SciencesNCL beilstein-journals.org/bjoc/articles/…
Having trouble crystallising your BCF adducts? Here is our heavy-atom version with para-bromine substituents. @ChemEurJ doi.org/10.1002/chem.2…
Our latest manuscript is now live on ChemRxiv! Title: Skeletal Transformation to Chiral Molecular Nanocarbons Huge kudos to our Ph.D. student Jun for his outstanding and persistent work! chemrxiv.org/engage/chemrxi…
Why Is Quantum Chemistry So Complicated? | Journal of the American Chemical Society #JACSPerspective pubs.acs.org/doi/10.1021/ja…
This isn’t your classic metal–ligand coordination bond. We made a non-metal-to-metal coordination bond. Now @NatureComms doi.org/10.1038/s41467… Many thanks to all co-authors, @SuomenAkatemia, @ERC_Research, @jyuscience, @jyunsc and @RiedelLab
Finally! It really exists in solution state! 😍
Check out the latest from Dean Tantillo's group: PeriRxn, a Tool for Assessing Pericyclicity through NICS and nMCBO in #JOrgChem ✅ Selected for #EditorsChoice! ✅ Part of our ongoing Physical Organic Chemistry: Never Out of Style special issue! go.acs.org/cZJ
After several years of studying superoxides and ozonide salts with organic cations as part of my doctoral thesis, it's nice to return to fluorine chemistry. Out now in ACS Organic & Inorganic Au pubs.acs.org/doi/full/10.10…
Excited to see that my fluorescent funnel was chosen as #CENChemPics of the week in @cenmag ! cen.acs.org/synthesis/Chem…
Alexander Krappe set up his separation funnel just as he always did to extract impurities from the compound he was synthesizing. Read more about this edition of #CENChemPics: cen.acs.org/synthesis/Chem…
Benzene, PAHs, macrocycles, nanorings, etc. We thought we understood aromaticity. BDF challenges what we see, what we measure, and what we believe about delocalized bonding. | ChemRxiv - go.shr.lc/3IFFvb5
Interested in doing P4 activation chemistry but unsure where to source the P4? Look who just published a first author paper on how to make P4 safely! Thanks to Tianze Song and Josh Goldberger for teaching me about tube furnaces! pubs.acs.org/doi/10.1021/ac…
Check out our new #preprint 📢😀"Bicyclo[1.1.1]pentane Ketones via Friedel-Crafts Acylation" #BCP #isostere @ChemRxiv chemrxiv.org/engage/chemrxi… great work by Freya and Karolina and coop with #PavelMykhailiuk @EnamineLtd 🇺🇦 supported by @Researchirel @ias_tum
Robert Kubica had a deal in place to drive for Ferrari in F1 in 2012 but the severe injuries he suffered in a rally crash dashed his dream 💔 Over a decade later and he's just won the most prestigious race in the world in a Ferrari ❤️
Molecular belts can go SUPERCOILED! We’ve nailed a 24-benzene and 24-thiophene fused molecular belt with a plectonemic geometry. Honored to contribute to this exciting work with Prof. Jiaobing Wang. onlinelibrary.wiley.com/doi/10.1002/an…
Our in-insect nanocarbon synthesis is now out in @ScienceMagazine. Enjoy our crazy campaign feeding molecules to insects densely packed with diverse enzymes and let them produce new functional compounds! Many thanks and huge congrats to all involved!! science.org/doi/10.1126/sc…
Nucleophilic substitution at a neopentyl-like electrophile ⁉️ Our new, bench-stable, bifunctional Iodo-BCP-TT reagent makes it possible! Our new, highly modular platform to access a broad range of BCP isosteres is now out in @NatureSynthesis! ⬇️⬇️⬇️ nature.com/articles/s4416…
beilstein-journals.org/bjoc/articles/… Interesting read: On the #photoluminescence in triarylmethyl-centered mono-, di-, and #multiradicals by Alexander J. C. Kuehne @TheColloid @uni_ulm et al. Published diamond open access 💎🔓 in #BJOC Thanks to all authors + referees involved 🏅

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